Preface xvi
A Note for Students xxi
1 Structure and Bonding; Acids and Bases 1
1.1 Atomic Structure 3
1.2 Electron Configuration of Atoms 5
1.3 Development of Chemical Bonding Theory 6
1.4 The Nature of Chemical Bonds 7
1.5 Forming Covalent Bonds: Valence Bond Theory 10
1.6 Hybridization: sp[superscript 3] Orbitals and the Structure of Methane 11
1.7 Hybridization: sp[superscript 3] Orbitals and the Structure of Ethane 12
1.8 Hybridization: sp[subscript 2] Orbitals and the Structure of Ethylene 13
1.9 Hybridization: sp Orbitals and the Structure of Acetylene 16
1.10 Polar Covalent Bonds: Electronegativity 17
1.11 Acids and Bases: The Bronsted--Lowry Definition 20
1.12 Acids and Bases: The Lewis Definition 24
2 The Nature of Organic Compounds: Alkanes 34
2.1 Functional Groups 35
2.2 Alkanes and Alkyl Groups: Isomers 41
2.3 Naming Branched-Chain Alkanes 46
2.4 Properties of Alkanes 49